On the 31Πu state in caesium dimer
نویسندگان
چکیده
Polarisation labelling spectroscopy technique was employed to study the 3$^{1}\Pi_{u}$ state of Cs$_2$ molecule. The main equlibrium constants are $T_e=20684.60$cm$^{-1}$, $\omega_e=30.61$cm$^{-1}$ and $R_e=5.27$\r{A}. Vibrational levels $v=4-35$ were found be subject strong perturbations by neighbouring electronic states. Energies 3094 rovibronic perturbed complex determined.
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ژورنال
عنوان ژورنال: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
سال: 2021
ISSN: ['1386-1425', '1873-3557']
DOI: https://doi.org/10.1016/j.saa.2021.119643